Chlorination with Sulfuryl Chloride. I. Chlorination of Aromatic Aldehydes
نویسندگان
چکیده
منابع مشابه
Direct and enantioselective organocatalytic alpha-chlorination of aldehydes.
The first direct enantioselective catalytic alpha-chlorination of aldehydes has been accomplished. The use of enamine catalysis has provided a new organocatalytic strategy for the enantioselective chlorination of aldehydes to generate alpha-chloro aldehydes, an important chiral synthon for chemical and medicinal agent synthesis. The use of imidazolidinone 3 as the asymmetric catalyst has been f...
متن کاملSalt Chlorination
Millions of people worldwide enjoy swimming pool activities every year. Traditionally, chlorine-containing chemicals have been used as the sanitizing agent. Some chlorine containing chemicals used include chlorine gas, sodium hypochlorite, calcium hypochlorite, lithium hypochlorite, and chlorinated isocyanurates. These chemicals enter the pool as a concentrated solution, or in the form of hypoc...
متن کاملChlorination of (Phebox)Ir(mesityl)(OAc) by Thionyl Chloride.
Pincer (Phebox)Ir(mesityl)(OAc) (2) (Phebox = 3,5-dimethylphenyl-2,6-bis(oxazolinyl)) complex, formed by benzylic C-H activation of mesitylene (1,3,5-trimethylbenzene) using (Phebox)Ir(OAc)2OH2 (1), was treated with thionyl chloride to rapidly form 1-(chloromethyl)-3,5-dimethylbenzene in 50% yield at 23 °C. A green species was obtained at the end of reaction, which decomposed during flash colum...
متن کاملOxidative Chlorination of Aromatic Compounds in Aqueous Media
An efficient method for the synthesis of chlorinated arenes is disclosed. The method involves the use of NaClO3 as oxidant and HCl as chlorinating agent in aqueous medium under mild conditions to chlorinate the aromatic compounds in good to excellent yields (75-96%). The reagent system is efficient, organic solvent-free and easy to handle.
متن کاملThe Chlorination of Water
Chlorine is most readily available in the form of chloride of lime (bleaching powder), which can readily be obtained commercially. This, if freshly made, should contain 33 per cent, of free or active chlorine. It loses its efficacy on keeping, especially during hot weather; but this loss may be retarded by the addition of 25 per cent, of quicklime. Samples of the bleaching powder used should be...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Nippon kagaku zassi
سال: 1960
ISSN: 0369-5387,2185-0917
DOI: 10.1246/nikkashi1948.81.9_1450